Piperazine-1,4-diium (R)-2-[4-(1-carboxylatomethoxy)phenoxy]propanoate

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Piperazine-1,4-diium (R)-2-[4-(1-car­boxy­l­atometh­oxy)phen­oxy]propano­ate

In the anion of the title mol-ecular salt, C(4)H(12)N(2) (2+)·C(11)H(10)O(6) (2-), the two acetate groups form torsion angles of 74.1 (1) and 7.1 (1)° with the central benzene ring, and the cation exhibits a chair conformation. In the crystal, N-H⋯O hydrogen bonds link the components into a two-dimensional supra-molecular network lying parallel to the ab plane. A number of C-H⋯O inter-actions c...

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1-(2-Aza­niumyleth­yl)piperazine-1,4-diium trinitrate

In the title salt, C(6)H(18)N(3) (3+)·3NO(3) (-), the piperazine ring adopts a chair conformation and the ethyl-ammonium group is equatorial relative to the piperazine ring, and in an all-trans conformation. In the crystal, strong charge-assisted N-H⋯O hydrogen bonds link the piperazinediium trications and the nitrate anions into a three-dimensional network.

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1-(4-Chloro­phen­yl)piperazine-1,4-diium tetra­chlorido­zincate(II) monohydrate

In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H⋯Cl, N-H⋯Cl, N-H⋯O and C-H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular π-π stacking inter-...

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The asymmetric unit of the title inorganic-organic hybrid compound, (C10H16N2O)[CoCl4]·H2O, consists of a tetrahedral [CoCl4](2-) anion, together with a [C10H18N2O](2+) cation and a water mol-ecule. Crystal cohesion is achieved through N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds between organic cations, inorganic anions and the water mol-ecules, building up a three-dimensional network.

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Piperazine-1,4-diium diacetate

In the title salt, C(4)H(12)N(2) (2+)·2C(2)H(3)O(2) (-), the piperazine-1,4-diium cation has 2/m symmetry with the NH(2) unit located on a mirror plane and the acetate anion has m symmetry with all non-H atoms and one H atom located on a mirror plane. The piperazine ring adopts a chair conformation. In the crystal, the cations are linked with the anions via N-H⋯O hydrogen bonding into chains pa...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812027213